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📖 Glossary

Terms, abbreviations, and definitions used throughout this study.


Contents


Battery & Electrochemistry

Term Definition
LiFePO₄ Lithium Iron Phosphate — a lithium-ion battery chemistry known for safety, longevity, and thermal stability. Also written as LFP.
4S Configuration Four cells connected in Series, producing ~12.8V nominal (3.2V × 4).
Parallel Configuration Multiple cells or blocks connected positive-to-positive and negative-to-negative, increasing capacity while maintaining voltage.
BMS Battery Management System — circuitry that monitors cell voltages, temperatures, and current, providing protection against overcharge, overdischarge, and overcurrent.
SOC State of Charge — the remaining capacity of a battery expressed as a percentage of its full capacity.
OCV Open Circuit Voltage — the voltage measured across battery terminals with no load connected and after sufficient rest time.
Nominal Voltage The typical operating voltage of a battery chemistry; 3.2V per cell for LiFePO₄.
Capacity (Ah) Ampere-hours — a measure of how much charge a battery can store. A 100Ah battery can theoretically deliver 100A for 1 hour or 10A for 10 hours.
Internal Resistance The opposition to current flow within a battery, measured in milliohms (mΩ). Lower is better.
Peukert Exponent A constant (k) describing how capacity decreases at higher discharge rates. k = 1.0 is ideal (no capacity loss); LiFePO₄ is typically 1.00–1.05.
Parasitic Draw Small continuous current consumption from connected devices when the system is nominally “off.”
Self-Discharge The gradual loss of charge in a battery when not in use, due to internal chemical reactions. LiFePO₄ has very low self-discharge (~2–3% per month).

Statistics & Analysis

Term Definition
OLS Ordinary Least Squares — a standard linear regression method that minimizes the sum of squared differences between observed and predicted values.
Coefficient of Determination — indicates how well the regression line fits the data. R² = 1.0 means perfect fit; R² = 0 means no linear relationship.
σ (Sigma) Standard Deviation — a measure of the spread or dispersion of a dataset. Lower σ means data points are closer to the mean.
SE Standard Error — the standard deviation of a statistic’s sampling distribution. Often reported for regression coefficients.
p-value The probability of observing results at least as extreme as measured, assuming the null hypothesis is true. Typically, p < 0.05 is considered statistically significant.
MA-60s Moving Average, 60 Seconds — a time-based trailing rolling mean applied to high-frequency data. Uses rolling('60s') in pandas, which adapts to variable sampling intervals.
Detrended Data with the linear trend removed, allowing analysis of residual variation around the trend.
Residual The difference between an observed value and the value predicted by a model.
Window Dependence The phenomenon where calculated statistics (like drift rate) vary depending on the time window selected for analysis.

Hardware & Sensors

Term Definition
Shelly Plus Uni A Wi-Fi-enabled sensor interface by Shelly, used here for voltage monitoring. Features ESP32 microcontroller with integrated ADC.
ADC Analog-to-Digital Converter — circuitry that converts continuous analog signals (like voltage) into discrete digital values.
ESP32 A popular microcontroller by Espressif with integrated Wi-Fi and Bluetooth, used in the Shelly Plus Uni.
Vref Reference Voltage — the known voltage that an ADC uses as a comparison standard. ESP32 has nominal 1100mV Vref with chip-to-chip variation of 1000–1200mV.
eFuse Calibration Factory calibration values burned into ESP32 chips that can improve ADC accuracy.
Home Assistant Open-source home automation platform used for data collection, logging, and integration in this study.
InfluxDB A time-series database often used with Home Assistant for long-term data storage.
Eco Mode A power-saving mode on Shelly devices that reduces power consumption but may affect sampling behavior. Enabled Dec 23, 2025 in this study.

Data & Measurement

Term Definition
Hourly Aggregate Data summarized per hour, typically as minimum, maximum, or mean values within that hour.
High-Frequency Data Raw sensor readings at the fastest available rate (~3 seconds in this study).
State-Change Logging A logging method where new records are only created when the measured value changes. Results in variable time intervals between records.
Cadence The timing interval between measurements. Can be fixed (e.g., every 10 seconds) or variable (state-change logging).
Spread The difference between maximum and minimum values within a time window. In this study: Spread = Max - Min for hourly data.
Mid-Voltage The arithmetic mean of minimum and maximum voltage: Mid = (Min + Max) / 2.
Quantization The discrete steps in ADC output. A 10mV quantization means the sensor can only report values in 10mV increments.
EMI Electromagnetic Interference — unwanted electrical noise that can affect sensor readings.
Artifact An anomaly in data caused by the measurement system rather than the phenomenon being measured.

Units & Conversions

Unit Name Notes
V Volts Electrical potential difference
mV Millivolts 1 mV = 0.001 V
A Amperes Electrical current
mA Milliamperes 1 mA = 0.001 A
Ah Ampere-hours Battery capacity
Milliohms Resistance (1 mΩ = 0.001 Ω)
°F Degrees Fahrenheit Temperature (used in this study)
°C Degrees Celsius Temperature (°C = (°F - 32) × 5/9)
UTC Coordinated Universal Time Standard time reference for high-frequency data
EST/EDT Eastern Standard/Daylight Time Local time zone for hourly data (UTC-5/UTC-4)

Temperature Conversion

°C = (°F - 32) × 5/9
°F = (°C × 9/5) + 32

Common Values

Description Value
LiFePO₄ cell nominal voltage 3.2 V
LiFePO₄ cell full charge 3.65 V
LiFePO₄ cell empty 2.5 V
4S pack nominal 12.8 V
4S pack full charge 14.6 V
4S pack empty 10.0 V
Freezing point (charge cutoff) 32°F / 0°C

See Also